@article{ad068c4f68f04dc5a4a64f097a28c42d,
title = "Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical study",
keywords = "hydrogen-deuterium exchange, supercritical water, pKa calculations, weak acids",
author = "Albuquerque, \{Pia R\} and Ramachandran, \{B. R.\} and Thomas Junk and Karsili, \{Tolga N. V.\}",
note = "Treatment of homo- and heterocyclic aromatic substrates with basic deuterium oxide under near- or supercritical conditions results in rapid base-catalyzed hydrogen-deuterium exchange (HDE) in aromatic and benzylic positions. It has been postulated that HDE follows a simple deprotonation-reprotonation mechanism, but little evidence has been provided to date.",
year = "2020",
month = mar,
day = "9",
doi = "10.1021/acs.jpca.9b10892",
language = "American English",
volume = "124",
journal = "Journal of Physical Chemistry C",
}